Porous Ni-based metal–organic frameworks reduce the oxygen evolution temperature of lithium perchlorate

Dalton Transactions 2026 Open access

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Authors: Nicholas A. Tomalia, Yulia Rakova, Ashley N. Tubman, Adam J. Matzger
DOI: 10.1039/d6dt01134a
Cited by: 1
References: 44

Abstract

yield. Framework porosity enables oxidizer melt-infiltration and promotes intimate nanoscale oxidizer-catalyst contact, enhancing catalytic effectiveness relative to the most effective nonporous Ni catalyst identified through Ni-salt screening. This approach demonstrates how framework porosity can be leveraged to enhance oxidizer-catalyst interactions and improve catalytic efficiency in oxygen-generating systems through structural design rather than solely through metal identity or loading, enabling lower-temperature oxygen release without compromising oxygen yield.

Fields of Study & Subjects

Electrocatalysts for Energy Conversion Advanced Battery Materials and Technologies Metal-Organic Frameworks: Synthesis and Applications

Publication details

Journal / source
Dalton Transactions
Publisher
Royal Society of Chemistry (RSC)
Volume
55
Issue
22
Pages
8604–8610
Publication date
1 January 2026
Language
EN