Exploration of the role of carboxylate bridges on the magnetisation dynamics of {LnIII2} (Ln = Tb, Dy, Ho, and Er) paddle-wheel single-molecule magnets: structure–property correlations

Dalton Transactions 2026

View at publisher
Authors: Vipanchi Vipanchi, Bapan Jana, Ganeshmoorthi Balan, Angshuman Roy Choudhury, Maheswaran Shanmugam, Kuduva R. Vignesh
DOI: 10.1039/d6dt01456a
Cited by: 1
References: 82

Abstract

Our studies on four {Ln 2 } paddle-wheel complexes highlight that the µ-carboxylate bridges provide several exchange paths to get the desired ferromagnetic coupling between the Ln( iii ) ions, which in turn favours the SMM behaviour for the Dy analog.

Fields of Study & Subjects

Magnetism in coordination complexes Lanthanide and Transition Metal Complexes Metal-Organic Frameworks: Synthesis and Applications

Publication details

Journal / source
Dalton Transactions
Publisher
Royal Society of Chemistry (RSC)
Volume
55
Issue
28
Pages
10602–10617
Publication date
1 January 2026
Language
EN