Nitroimine-encoded conformational locking: a molecular switch for planarity and stability

Materials Horizons 2026

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Authors: Jatinder Singh, Richard J. Staples, Jean'ne M. Shreeve
DOI: 10.1039/d6mh00935b
Cited by: 1
References: 31

Abstract

motion in tetrazine frameworks. This structural constraint suppresses molecular motion and modulates thermal stability, establishing a framework-level strategy for controlling reactive molecular systems. This study shifts energetic-material design from substituent-centric optimization toward connectivity-driven conformational control.

Fields of Study & Subjects

Molecular Junctions and Nanostructures Supramolecular Chemistry and Complexes Crystallography and molecular interactions

Publication details

Journal / source
Materials Horizons
Publisher
Royal Society of Chemistry (RSC)
Volume
13
Issue
17
Pages
8618–8625
Publication date
1 January 2026
Language
EN