Ball-milling synthesis of α-bromoacrylates from solvent-free in situ prepared ethyl diethylbromophosphonate

RSC Mechanochemistry 2026 Open access

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Authors: Marie Caldiero, Jean-Philippe Bouillon, Thomas Castanheiro
DOI: 10.1039/d6mr00029k
Cited by: 1
References: 82

Abstract

A mechanosynthesis of α-bromoacrylates was described from commercially available triethyl phosphonoacetate through a ball-milling-assisted bromination/HWE one-pot process. α-iodo- and α-chloroacrylates were also accessible using NIS and NCS.

Fields of Study & Subjects

Vanadium and Halogenation Chemistry Crystallography and molecular interactions Coordination Chemistry and Organometallics

Publication details

Journal / source
RSC Mechanochemistry
Publisher
Royal Society of Chemistry (RSC)
Volume
3
Issue
3
Pages
459–465
Publication date
1 January 2026
Language
EN