Base-promoted cascade haloamination/β-elimination of alkenyl thianthrenium salts: access to ( Z )-β-chloroenamines

Organic & Biomolecular Chemistry 2026

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Authors: Qing-Long Lv, Yue Fan, Yuanbing Qi, Yue Lu, Yinjiang Xue, Ao-Tong Shi, Hongqiang Xia, Dianjun Li
DOI: 10.1039/d6ob00027d
Cited by: 2
References: 43

Abstract

A catalyst-free base-promoted cascade chloramination/β-elimination of alkenyl thianthrenium salts with N- chlorosulfonamides to generate ( Z )- β -chloro-enamine products due to the π–π interaction has been developed with excellent stereoselectivity.

Fields of Study & Subjects

Catalytic C–H Functionalization Methods Synthesis and Catalytic Reactions Vanadium and Halogenation Chemistry

Publication details

Journal / source
Organic & Biomolecular Chemistry
Publisher
Royal Society of Chemistry (RSC)
Volume
24
Issue
11
Pages
2225–2229
Publication date
1 January 2026
Language
EN