Stereodivergent (3 + 2)-cycloaddition of donor–acceptor cyclopropanes and citral imines catalyzed by Yb(NTf 2 ) 3 /PyBOX

Organic & Biomolecular Chemistry 2026

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Authors: Pavel G. Sergeev, Roman A Novikov, Yury V. Tomilov
DOI: 10.1039/d6ob00121a
Cited by: 2
References: 122

Abstract

The diastereoselectivity mode of (3 + 2)-cycloaddition between donor–acceptor cyclopropanes and newly obtained citral imines is switched depending on the electronic nature of the substituent at the nitrogen atom in the citral imine.

Fields of Study & Subjects

Cyclopropane Reaction Mechanisms Catalytic Alkyne Reactions Radical Photochemical Reactions

Publication details

Journal / source
Organic & Biomolecular Chemistry
Publisher
Royal Society of Chemistry (RSC)
Volume
24
Issue
14
Pages
2981–2989
Publication date
1 January 2026
Language
EN