Photo-induced silylation cyclization of indole-tethered 1,6-enynes to access silylated pyrrolo[1,2- a ]indole derivatives
Abstract
]indoles with good selectivity/yields. Additionally, the HH-NOESY, scaled-up operation, and complex molecular derivatization were carried out to examine the skeleton and application of the final silylated fused cycles. Finally, radical inhibition/capture studies provided insight into the silylation pathway of this cascade system.
Fields of Study & Subjects
Catalytic C–H Functionalization Methods
Radical Photochemical Reactions
Organoboron and organosilicon chemistry
Publication details
- Journal / source
- Organic & Biomolecular Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Volume
- 24
- Issue
- 13
- Pages
- 2665–2668
- Publication date
- 1 January 2026
- Language
- EN