Stable nickel complexes of a siliconoid/silylene hybrid ligand: competent hydrosilylation catalysts for terminal olefins

Inorganic Chemistry Frontiers 2026 Open access

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Authors: Luisa Giarrana, Dennis Welterlich, Michael Zimmer, Bernd Morgenstern, David Scheschkewitz
DOI: 10.1039/d6qi00025h
Cited by: 0
References: 86

Abstract

The first stable nickel complex with siliconoid/silylene hybrid ligand is reported. The auxiliary 1,5- cod ligand is readily exchanged by PPh 3 and CO, respectively. It shows considerable activity as catalyst in the hydrosilylation of terminal alkenes.

Fields of Study & Subjects

Organometallic Complex Synthesis and Catalysis Synthesis and characterization of novel inorganic/organometallic compounds Organoboron and organosilicon chemistry

Publication details

Journal / source
Inorganic Chemistry Frontiers
Volume
13
Issue
8
Pages
3462–3472
Publication date
1 January 2026
Language
EN