Unveiling the unique promotional role of samarium in polyoxometalate catalysed selective oxidation of benzyl alcohol

Inorganic Chemistry Frontiers 2026

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Authors: Su-Yuan Feng, Z.-Q. Rong, Qinwei Chen, Xiao-Yuan Wu, Weiming Wu, Sa-Sa Wang, Can‐Zhong Lu
DOI: 10.1039/d6qi00220j
Cited by: 1
References: 29

Abstract

The incorporation of Sm 3+ into POM boosts 1 O 2 generation via inducing electron depletion at W sites with invariable reaction pathway, while the introduction of Ce 3+ significantly suppresses 1 O 2 production owing to the Fenton-like homolysis of H 2 O 2 .

Fields of Study & Subjects

Polyoxometalates: Synthesis and Applications Oxidative Organic Chemistry Reactions Metal-Catalyzed Oxygenation Mechanisms

Publication details

Journal / source
Inorganic Chemistry Frontiers
Publisher
Royal Society of Chemistry (RSC)
Volume
13
Issue
11
Pages
5030–5038
Publication date
1 January 2026
Language
EN