Ethylene carbonate splitting and Claisen-type self-addition of γ-butyrolactone promoted by an oxygen-bridged Ga/P FLP

Inorganic Chemistry Frontiers 2026 Open access

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Authors: Julian Buth, Beate Neumann, Jan-Hendrik Lamm, Georg Stammler, Yury V. Vishnevskiy, Norbert W. Mitzel
DOI: 10.1039/d6qi00380j
Cited by: 1
References: 48

Abstract

The geminal frustrated Lewis pair [(Me 3 Si) 2 CH] 2 Ga–O–P t Bu 2 is capable of reversible activations, bond cleavages, and multistep substrate transformations, including the splitting of ethylene carbonate and a Claisen-type addition of γ-butyrolactone.

Fields of Study & Subjects

Organoboron and organosilicon chemistry Synthesis and characterization of novel inorganic/organometallic compounds Silicone and Siloxane Chemistry

Publication details

Journal / source
Inorganic Chemistry Frontiers
Publisher
Royal Society of Chemistry (RSC)
Volume
13
Issue
12
Pages
5352–5360
Publication date
1 January 2026
Language
EN