Epimeric cation stereocontrol enables tunable phase transition enthalpy and polar ferroelectric frameworks

Inorganic Chemistry Frontiers 2026

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Authors: Zheng-Hui Hu, Chang-Chun Fan, Hongfei Zhao, Ze-Yu Jia, Ting Hai, Yu‐Hui Tan, Dong-Lan Zhang, Chao Shi
DOI: 10.1039/d6qi01007e
Cited by: 3
References: 43

Abstract

Two 2D rare-earth double perovskites are constructed using α-/β-tropine epimers, among which the polar (α-tropine) 4 KCe(NO 3 ) 8 exhibits superior physical properties arising from its loose hydrogen-bonded framework.

Fields of Study & Subjects

Perovskite Materials and Applications Inorganic Chemistry and Materials Layered Double Hydroxides Synthesis and Applications

Publication details

Journal / source
Inorganic Chemistry Frontiers
Publisher
Royal Society of Chemistry (RSC)
Volume
13
Issue
17
Pages
7366–7375
Publication date
1 January 2026
Language
EN