Blue light-promoted [2 + 4] cycloaddition of phosphenes and N -acylimines: highly diastereoselective access to 3,4-dihydro-1,5,2-oxazaphosphinine 2-oxides

Organic Chemistry Frontiers 2026

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Authors: Mengyao Zhang, Chongjie Su, Hongguang Du, Jiaxi Xu
DOI: 10.1039/d6qo00019c
Cited by: 4
References: 39

Abstract

Blue light-promoted concerted [2 + 4] heteroatom Diels–Alder cycloaddition of N -acylimines and phosphenes generated from phosphoryl aryl(diazo)methanes, affording highly diastereoselective trans -3,4-dihydro-1,5,2-oxazaphosphinine 2-oxides.

Fields of Study & Subjects

Radical Photochemical Reactions Organophosphorus compounds synthesis Catalytic Cross-Coupling Reactions

Publication details

Journal / source
Organic Chemistry Frontiers
Publisher
Royal Society of Chemistry (RSC)
Volume
13
Issue
7
Pages
2108–2113
Publication date
1 January 2026
Language
EN