Re( i )-catalyzed C–C and C–S bond formation via regioselective C(sp 2 )–H hydroalkylation and hydrothiolation

Organic Chemistry Frontiers 2026

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Authors: Khushboo Tiwari, Suman Bhowmick, Mayank Singh, Rajani Kant, Dharmendra Kumar Tiwari
DOI: 10.1039/d6qo00268d
Cited by: 1
References: 44

Abstract

A Re( i )-catalysed dual hydroalkylation method enables Markovnikov-selective O–C(sp 2 )–H functionalisation of phenols and anti-Markovnikov hydroalkylation of thiophenols. Biologically important phenols also undergo efficient ortho -functionalisation.

Fields of Study & Subjects

Sulfur-Based Synthesis Techniques Catalytic C–H Functionalization Methods Cyclopropane Reaction Mechanisms

Publication details

Journal / source
Organic Chemistry Frontiers
Publisher
Royal Society of Chemistry (RSC)
Volume
13
Issue
12
Pages
3780–3785
Publication date
1 January 2026
Language
EN