Modular and stereoselective synthesis of Si-/Ge-glycosides via palladium-catalyzed bis-silylation and bis-germanylation of glycals

Organic Chemistry Frontiers 2026

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Authors: Weiwei Lv, Xueting Zhu, Wendong Peng, Dong Zhang, Youlin Yan, Jing Lu, Wanying Yang, Qiaoyun Li, Guolin Cheng
DOI: 10.1039/d6qo00406g
Cited by: 1
References: 59

Abstract

Palladium-catalyzed bis-silylation/bis-germanylation of glycals enables modular synthesis of Si-/Ge-glycosides. Using ONBD as a switch and an ethylene surrogate gives ( Z ) - β-substituted vinylsilane/germane glycosides under mild conditions.

Fields of Study & Subjects

Carbohydrate Chemistry and Synthesis Catalytic Cross-Coupling Reactions Organoboron and organosilicon chemistry

Publication details

Journal / source
Organic Chemistry Frontiers
Publisher
Royal Society of Chemistry (RSC)
Volume
13
Issue
13
Pages
4102–4108
Publication date
1 January 2026
Language
EN