Intriguing three-component four-layer stacking nanostructures formed by the self-assembly of main-chain liquid-crystalline polyurethane elastomers, as analyzed by two-dimensional small-angle X-ray scattering

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Authors: Yuki Hasegawa, Tomoka Noda, Seiji Iseki, Tatsuya Endo, Yume Sugino, Shinichi Sakurai
Cited by: 1
References: 53

Abstract

of the LC phase is also ascribed. Thus, many effects due to physical constraints in the main-chain LC polymer were found. To further reveal the details of the nanostructure, the 2D-SAXS patterns exhibiting the X-shaped feature were measured during uniaxial elongation. Then, it was found that the crossing angle between the two representative directions in which the reflection peaks appeared increased and leveled off at the limiting value of 64°, which implies an inclination angle of 32° for the mesogenic units in the LC layer.

Fields of Study & Subjects

Advanced Materials and Mechanics Polymer composites and self-healing Block Copolymer Self-Assembly

Publication details

Journal / source
RSC Advances
Publisher
Royal Society of Chemistry (RSC)
Volume
16
Issue
23
Pages
20840–20854
Publication date
1 January 2026
Language
EN