Atroposelective construction of indole-fused diazocines via gold( i )-catalysed 8- endo -dig cyclisation

Chemical Science 2026 Open access

Read full text
Authors: Silvia Meraviglia, Alessandra Romanelli, Paola Iannelli, Silvia Rizzato, Alessandro Contini, Giorgio Abbiati, Valentina Pirovano
DOI: 10.1039/d6sc00020g
Cited by: 1
References: 94

Abstract

Gold( i )-catalysed atroposelective cyclisation affords indole-fused diazocines featuring a conformationally constrained diazocine core, combining high enantioselectivity, configurational stability, and potential for molecular recognition.

Fields of Study & Subjects

Axial and Atropisomeric Chirality Synthesis Catalytic Alkyne Reactions Catalytic C–H Functionalization Methods

Publication details

Journal / source
Chemical Science
Publisher
Royal Society of Chemistry (RSC)
Volume
17
Issue
23
Pages
11580–11590
Publication date
1 January 2026
Language
EN