Solvation-driven interphase engineering and mechanical failure pathways in large-scale anode-free lithium metal batteries

Chemical Science 2026 Open access

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Authors: Nattanon Joraleechanchai, Nuttida Matkhaw, Thitiphum Sangsanit, Worapol Tejangkura, Montree Sawangphruk
DOI: 10.1039/d6sc00025h
Cited by: 3
References: 46

Abstract

at the jelly-roll level), nearly 100% coulombic efficiency, and compliance with UN38.3 impact-safety standards. Importantly, we identify lithium-plating-induced mechanical expansion-not interfacial instability-as the dominant failure pathway, establishing a direct link between molecular solvation structure and macroscopic structural integrity. These findings define solvation-driven interphase engineering as a practical route toward safe, high-energy anode-free lithium-metal batteries.

Fields of Study & Subjects

Advanced Battery Materials and Technologies Advancements in Battery Materials Inorganic Chemistry and Materials

Publication details

Journal / source
Chemical Science
Publisher
Royal Society of Chemistry (RSC)
Volume
17
Issue
17
Pages
8453–8471
Publication date
1 January 2026
Language
EN