Visible-light-driven valorization of 5-hydroxymethylfurfural over a hollow Co 3 O 4 @Zn 3 In 2 S 6 nanocage in base-free water under an air atmosphere

Read full text
Authors: Rong Dang, Kexin Fan, Yanning Wang, Guoxiong Zhu, Liu Liu, Zifu Hu, Taolian Guo, Wu Chen, Fengxiang Chen
Cited by: 2
References: 53

Abstract

, which is beneficial to generate strong interfacial interaction and facilitate the separation of electron-hole pairs. Characteristic analysis and density functional theory (DFT) calculations elucidate that the enhanced built-in electric field (IEF) and S-scheme charge transfer mechanism within the ZC heterojunction effectively drive the selective photo-oxidation of HMF to DFF. This work offers an efficient strategy to design heterojunction photocatalysts for highly effective oxidation of HMF under mild conditions.

Fields of Study & Subjects

Catalysis for Biomass Conversion Radical Photochemical Reactions Synthesis and Characterization of Pyrroles

Publication details

Journal / source
Chemical Science
Publisher
Royal Society of Chemistry (RSC)
Volume
17
Issue
16
Pages
8076–8083
Publication date
1 January 2026
Language
EN