Homoleptic seven-coordinate Ti(0) and Zr(0) through a new stabilization mode

Chemical Science 2026 Open access

Read full text
Authors: Ivan Antsiburov, Raphael Bühler, Johannes Stephan, Maxim Erdyakov, Christian Gemel, Samia Kahlal, Olivier Cador, Thierry Guizouarn, Jean-Yves Saillard, Karsten Meyer, Roland A. Fischer
DOI: 10.1039/d6sc00226a
Cited by: 2
References: 51

Abstract

centers into the constructive combinations of the diffuse 4p orbitals of the Ga(i) centers. This unique cooperative feature of the all-Ga metalloligand sphere marks a clear distinction from the bonding properties of formally isolobal carbonyls, phosphines, or N-heterocyclic carbenes.

Fields of Study & Subjects

Organometallic Complex Synthesis and Catalysis Coordination Chemistry and Organometallics Synthetic Organic Chemistry Methods

Publication details

Journal / source
Chemical Science
Publisher
Royal Society of Chemistry (RSC)
Volume
17
Issue
18
Pages
8989–8997
Publication date
1 January 2026
Language
EN