Isolation of arylhalodiphosphenes: periodic trends in R–PP–X bonding (X = Cl, Br, I)

Chemical Science 2026 Open access

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Authors: John S. Wenger, Nina Gaschik, William J. Rowe, Agamemnon E. Crumpton, Bono van IJzendoorn, Meera Mehta
DOI: 10.1039/d6sc00723f
Cited by: 1
References: 79

Abstract

FluInd*)P[double bond, length as m-dash]PX (X = Cl, Br, I) represent the first fully characterized, crystalline arylhalodiphosphenes and serve to advance the state of low-coordinate phosphorus chemistry.

Fields of Study & Subjects

Synthesis and characterization of novel inorganic/organometallic compounds N-Heterocyclic Carbenes in Organic and Inorganic Chemistry Organometallic Complex Synthesis and Catalysis

Publication details

Journal / source
Chemical Science
Publisher
Royal Society of Chemistry (RSC)
Volume
17
Issue
15
Pages
7475–7485
Publication date
1 January 2026
Language
EN