The characterisation and reactivity of a Rh iii η 1 -σ-alkane complex and the role of a structurally responsive phosphine ligand in solid-state molecular organometallic chemistry

Chemical Science 2026 Open access

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Authors: Joe C. Goodall, M. Arif Sajjad, Samantha K. Furfari, Kristof M. Altus, Theo S. C. Hatcher, Graham J. Tizzard, Samuel J. Page, Mark R Warren, Jason M. Lynam, Stuart A. Macgregor, Andrew S. Weller
DOI: 10.1039/d6sc02133f
Cited by: 1
References: 76

Abstract

to a weakly coordinating σ-alkane. These reversible bond activations of the chelating ligand in response to changes in the co-ligands demonstrate that significant structural reorganisation is possible in the crystalline environment.

Fields of Study & Subjects

Organometallic Complex Synthesis and Catalysis Organoboron and organosilicon chemistry Synthesis and characterization of novel inorganic/organometallic compounds

Publication details

Journal / source
Chemical Science
Publisher
Royal Society of Chemistry (RSC)
Volume
17
Issue
23
Pages
11600–11611
Publication date
1 January 2026
Language
EN