Synthesis, characterization, and imidogen photochemistry of a hydrazoic acid adduct of Rh 2

Chemical Science 2026 Open access

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Authors: Arpan Paikar, Phong Thai, Matthew T. Figgins, Bodhisattwa Mandal, Matthew Lekas, Joseph Reibenspies, Gerard Van Trieste, David Charles Powers
DOI: 10.1039/d6sc02258h
Cited by: 1
References: 64

Abstract

Synthesis of the first crystalline transition metal complex of hydrazoic acid provides a platform to photogenerate metal imidogen complexes proposed in metal-cataylzed NH-transfer.

Fields of Study & Subjects

Radical Photochemical Reactions Catalytic C–H Functionalization Methods Catalytic Cross-Coupling Reactions

Publication details

Journal / source
Chemical Science
Publisher
Royal Society of Chemistry (RSC)
Volume
17
Issue
23
Pages
11655–11662
Publication date
1 January 2026
Language
EN