Enantioselective synthesis of silicon-stereogenic sulfur-containing silanes via organocatalytic remote C–H sulfenylation of arenes

Chemical Science 2026 Open access

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Authors: Shu-Kun Li, Xin-Yu Zhang, Qing-Yun Cai, Deren Chu, Yu‐Xuan Huo, Fan Wang, Xue-Qing Gong, Zhi‐Min Chen
DOI: 10.1039/d6sc03998g
Cited by: 1
References: 94

Abstract

sequential desymmetrization and kinetic resolution processes. Density functional theory (DFT) calculations further demonstrate that multiple weak C-H⋯π interactions, together with the torsional distortion of the substrate, are crucial for the observed enantioselectivity.

Fields of Study & Subjects

Sulfur-Based Synthesis Techniques Catalytic C–H Functionalization Methods Radical Photochemical Reactions

Publication details

Journal / source
Chemical Science
Publisher
Royal Society of Chemistry (RSC)
Volume
17
Issue
36
Pages
17287-17296
Publication date
1 January 2026
Language
EN