A 4,4-connected 2D POM-based complex with synergistic mixed-valence Cu I /Cu II for mild and efficient catalytic oxidation of phenols

Journal of Materials Chemistry A 2026

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Authors: Jiayu Sun, Si-Yu Sun, Zhong Zhang, Mei-tong Li, Guo-Cheng Liu, Xiu-Li Wang
DOI: 10.1039/d6ta00645k
Cited by: 18
References: 47

Abstract

A 4,4-connected 2D POM-based complex incorporating mixed-valence copper centers was successfully synthesized, exhibiting high-performance oxidation of 2,3,6-TMP to TMBQ with 98% conversion and >99% selectivity in 13 minutes at 50 °C.

Fields of Study & Subjects

Metal-Organic Frameworks: Synthesis and Applications Metal-Catalyzed Oxygenation Mechanisms Covalent Organic Framework Applications

Publication details

Journal / source
Journal of Materials Chemistry A
Publisher
Royal Society of Chemistry (RSC)
Volume
14
Issue
24
Pages
15000–15007
Publication date
1 January 2026
Language
EN