Revisiting the Butler–Volmer equation

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Authors: Silvio Heinschke, Jörg J. Schneider
Cited by: 5
References: 30

Abstract

An analytical reference point for the Butler–Volmer equation is derived introducing the golden ratio φ . It allows to estimate the exchange current density for reversible electrochemical processes with low overpotential and symmetric charge transfer.

Fields of Study & Subjects

Electrochemical Analysis and Applications Electrodeposition and Electroless Coatings CO2 Reduction Techniques and Catalysts

Publication details

Journal / source
Journal of Materials Chemistry A
Publisher
Royal Society of Chemistry (RSC)
Volume
14
Issue
25
Pages
15700–15705
Publication date
1 January 2026
Language
EN