Engineering hierarchical porosity in MOFs for host–guest chemistry with large organometallic complexes

Journal of Materials Chemistry A 2026 Open access

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Authors: Jakob Blaschke, Maria Asghar, Zheao Huang, Stephen Nagaraju Myakala, Shaghayegh Naghdi, Thomas Schachinger, Hanspeter Kählig, Olga Lanaridi, Andreas Limbeck, Jérôme Durand, Philippe Serp, Florian Libisch
+2 more Doğukan Hazar Apaydın, Dominik Eder
DOI: 10.1039/d6ta02595a
Cited by: 1
References: 64

Abstract

RR experiments show CO as the main product with high selectivity when using TEOA as a sacrificial agent. This work demonstrates the potential of engineering hierarchical porosity in MOFs for immobilizing large, catalytically active molecular species in a stable and well-defined environment.

Fields of Study & Subjects

Metal-Organic Frameworks: Synthesis and Applications Mesoporous Materials and Catalysis Covalent Organic Framework Applications

Publication details

Journal / source
Journal of Materials Chemistry A
Publisher
Royal Society of Chemistry (RSC)
Volume
14
Issue
41
Pages
27667–27682
Publication date
1 January 2026
Language
EN