Single-site CO 2 photoconversion to CH 4 using a triphenylamine and Co-metalated porphyrin-based donor–acceptor conjugated microporous polymer
Abstract
This study presents the development of a Co( ii ) single-atom-based conjugated microporous polymer, which achieves over 99% selectivity in CO 2 -to-CH 4 photoconversion, as supported by in situ DRIFTS and DFT studies.
Fields of Study & Subjects
Covalent Organic Framework Applications
Advanced Photocatalysis Techniques
Carbon dioxide utilization in catalysis
Publication details
- Journal / source
- Journal of Materials Chemistry A
- Publisher
- Royal Society of Chemistry (RSC)
- Volume
- 14
- Issue
- 51
- Pages
- 34921–34933
- Publication date
- 1 January 2026
- Language
- EN