Irreversible thermochromic Pb 2 Sn 2 O 6 · x H 2 O: competition between weak ligand H 2 O and lone-pair electrons
Abstract
Irreversible thermochromism in Pb 2 SnO 6 · x H 2 O demonstrates the conduction band gap narrowing effect in hybridizing lone-pair electrons in 6s–6p orbitals with the competition between the ligand of crystalline water and oxygen vacancies.
Fields of Study & Subjects
Polyoxometalates: Synthesis and Applications
Pigment Synthesis and Properties
Catalysis and Oxidation Reactions
Publication details
- Journal / source
- Journal of Materials Chemistry C
- Publisher
- Royal Society of Chemistry (RSC)
- Volume
- 14
- Issue
- 17
- Pages
- 7370–7377
- Publication date
- 1 January 2026
- Language
- EN