Epitaxial configuration of unidirectionally aligned MoS2 monolayer on sapphire
Abstract
Highly oriented MoS2 monolayer (ML) on the sapphire(0001) substrate was grown by metal-organic chemical vapor deposition. The epitaxial configuration of ML-MoS2/sapphire has been studied using low-energy electron diffraction (LEED) combined with first-principles calculations. LEED analysis based on the dynamical diffraction theory revealed that the MoS2 ML is grown with the epitaxial relationship of MoS2 [112¯0] // Al2O3 [112¯0] and MoS2 [11¯00] // Al2O3 [11¯00] and that the formation of antiparallel (inversion) domains is effectively suppressed. The observed epitaxial relationship is insensitive to the direction of surface steps on the sapphire substrate.
Fields of Study & Subjects
2D Materials and Applications
Graphene research and applications
Catalysis and Hydrodesulfurization Studies
Publication details
- Journal / source
- Journal of Applied Physics
- Publisher
- AIP Publishing
- Volume
- 139
- Issue
- 2
- Publication date
- 12 January 2026
- Language
- EN