Hydrate/moisture co-assisted synthesis enables humid-air stability of halide solid-state electrolytes

National Science Review 2026 Open access

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Authors: Xiangzhen Zhu, Chao Liu, Xiaolong Yan, Junyi Yue, Mingying Zhang, Simeng Zhang, Yueyue Wang, Han Wu, Yue Gong, Yanlong Wu, Xinmiao Wang, Shengjie Xia
+7 more Shanshan Wang, Zaifa Wang, Changtai Zhao, Jianwen Liang, Songbai Han, Xueliang Sun, Xiaona Li
DOI: 10.1093/nsr/nwag209
Cited by: 4
References: 51

Abstract

ABSTRACT Halide solid-state electrolytes (HSSEs) combine high ionic conductivity with wide electrochemical stability windows, making them promising candidates for all-solid-state lithium batteries (ASSLBs). However, their poor humid-air stability demands ultra-dry processing environments, severely limiting industrial scalability. Here, we report a water-assisted synthesis strategy to construct a zirconium-based core-shell structured HSSE, Li2Zr1.5OCl6@Li2CO3 (LZOC-H), under industrially viable dry-room conditions (dew point

Fields of Study & Subjects

Advanced Battery Materials and Technologies Thermal Expansion and Ionic Conductivity Advancements in Battery Materials

Publication details

Journal / source
National Science Review
Publisher
Oxford University Press (OUP)
Volume
13
Issue
10
Pages
nwag209–nwag209
Publication date
21 April 2026
Language
EN