Goldstone-Mediated Polar Instability in Hexagonal Barium Titanate

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Authors: Struan Simpson, Urmimala Dey, Robin Sjökvist, Jonathan Wright, C. Ritter, Richard Beanland, Nicholas C. Bristowe, Mark S. Senn
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Abstract

We discover a rare structural manifestation of the Goldstone paradigm in a hexagonal polytype of the prototypical ferroelectric BaTiO_{3}. First-principles calculations confirm the Goldstone character of the order parameter, while our high-resolution diffraction measurements unveil an unusual reentrant Goldstone regime manifesting as a quasicontinuous domain texture in the vicinity of the ferroelectric transition. We develop a minimal Landau model that encapsulates these observations, illustrating how U(1) symmetry can be restored at the ferroelectric transition. Our findings demonstrate how exotic Goldstone physics can be unlocked in systems dominated by highly anharmonic interactions, presenting a promising pathway to stabilize emergent polar topologies in bulk materials.

Fields of Study & Subjects

Ferroelectric and Piezoelectric Materials Multiferroics and related materials Magnetic and transport properties of perovskites and related materials

Publication details

Journal / source
Physical Review Letters
Volume
136
Issue
11
Pages
116101–116101
Publication date
12 February 2026
Language
EN