Algebraic to exponential decay of spatial correlations in one-dimensional and confined hard-core fluids: A Laplace-pole analysis

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Authors: Ana M. Montero, Andrés Santos
Cited by: 2
References: 13

Abstract

We derive the asymptotic behavior of the radial distribution function g(x) for one-dimensional (1D) hard-rod systems and related quasi-one-dimensional geometries at high packing fractions using Laplace transform techniques and pole analysis. By identifying the poles and residues of the Laplace transform in the limit of small void fraction, we obtain compact representations of g(x) in terms of the Jacobi elliptic theta function θ_{3}. This formulation naturally captures the two regimes governing the oscillatory decay toward unity: an intermediate algebraic decay and a long-distance exponential decay, consistent with previous results for the Tonks gas. Our approach provides a unified framework that (i) expresses g(x) in a single well-tabulated special function, (ii) links spatial correlations directly to the pole structure in complex Laplace space, offering clear physical insight into decay rates and oscillation frequencies, and (iii) generalizes straightforwardly to 1D binary mixtures and confined hard-disk systems, where direct Gaussian decompositions are cumbersome. The equivalence between the theta-function representation and the Gaussian superposition of [L. Bouzar et al., Phys. Rev. E 112, L042105 (2025)2470-004510.1103/bjbt-61d9] is established via the Poisson summation formula, highlighting the versatility and conceptual advantages of the Laplace-pole framework.

Fields of Study & Subjects

Phase Equilibria and Thermodynamics Statistical Mechanics and Entropy Material Dynamics and Properties

Publication details

Journal / source
Physical review. E
Publisher
American Physical Society (APS)
Volume
113
Issue
6
Pages
064133–064133
Publication date
27 May 2026
Language
EN