Equivalence of Discrete and Continuous Otto-like Engines Assisted by Catalysts: Mapping Catalytic Advantages from the Discrete to the Continuous Framework

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Authors: Marcin Łobejko, Tanmoy Biswas, Michał Horodecki
Cited by: 1
References: 67

Abstract

The catalytic extension of a discrete two-stroke engine employs a cyclic auxiliary system that remains thermally decoupled and performs no work, yet enhances power and efficiency beyond its noncatalytic counterpart. While discrete models are analytically tractable, they remain experimentally challenging due to the precise control required over individual strokes. Continuous engines, simultaneously coupled to heat baths and a driving field, offer a more experimentally feasible alternative. Here, we establish a unified framework connecting discrete and continuous machines-with and without a catalyst-by mapping unitary strokes and thermalization steps onto an interaction Hamiltonian and Markovian dissipation. Replacing probability flows with probability currents yields a continuous analog of catalytic Otto-like schemes. Focusing on the simplest catalytic extension, we demonstrate that catalytic enhancement persists in the continuous regime. Our results demonstrate how discrete models offer valuable insights for analyzing the performance of continuous thermal machines.

Fields of Study & Subjects

Catalysis and Oxidation Reactions Zeolite Catalysis and Synthesis Catalytic Processes in Materials Science

Publication details

Journal / source
Physical Review Letters
Publisher
American Physical Society (APS)
Volume
136
Issue
18
Pages
180402–180402
Publication date
9 April 2026
Language
EN