Minimal model of universal viscous liquid dynamics

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Authors: Ulf R. Pedersen
Cited by: 0
References: 71

Abstract

When liquids are cooled and crystallization is avoided, their dynamics slow dramatically and the material eventually solidifies into an amorphous glass. Experiments show that chemically distinct glass-forming liquids share universal features in both the spectral shape and the temperature dependence of the primary structural relaxation. We introduce Randium, a generic, energetically coarse-grained minimal model of viscous liquids. The model, inspired by results from atomistic molecular-dynamics simulations, is implemented on a two-dimensional lattice with Gaussian-distributed nearest-neighbor interactions. Temperature is the only control parameter, and at low temperatures, dynamic facilitation and dynamical heterogeneity emerge from simple nearest-neighbor rearrangements. The relaxation spectra obey time-temperature superposition, and they reproduce shapes observed experimentally for chemically distinct systems. The temperature dependence of the structural-relaxation time follows parabolic scaling, and the relaxation time grows exponentially with the heterogeneity length scale. The mean-squared displacement collapses onto the universal master curve of the random barrier model. The absence of elasticity-induced facilitation in Randium shows that this is not required for universal viscous-liquid dynamics. Other explanations for universal relaxation are discussed in light of Randium.

Fields of Study & Subjects

Material Dynamics and Properties Advanced Physical and Chemical Molecular Interactions Theoretical and Computational Physics

Publication details

Journal / source
Physical Review Research
Publisher
American Physical Society (APS)
Volume
8
Issue
3
Publication date
4 August 2026
Language
EN