Synthesis and structure of {methyl ( Z )-2-[4-(dimethylamino)benzylidene]hydrazine-1-carbodithioate-κ 2 N 2 , S }bis(triphenylphosphine-κ P )copper(I) nitrate carbon tetrachloride monosolvate

Acta Crystallographica Section E Crystallographic Communications 2026 Open access

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Authors: Liji Muthirakalayil Abraham, Banmankhraw Dkhar, Amirthalingam Arunkumar, Thangaraja Chinnathangavel, Kolandaivelu Saminathan, Marappan Velusamy, Venugopal Rajendiran
DOI: 10.1107/s2056989026000228
Cited by: 1
References: 23

Abstract

In the title compound, [Cu(C 11 H 15 N 3 S 2 ){P(C 6 H 5 ) 3 } 2 ]NO 3 ·CCl 4 , the carbon tetrachloride solvent molecule is presumed to have originated as an impurity in the chloroform solvent used. The coordination environment around the copper(I) ion is a distorted CuNSP 2 tetrahedron, with a τ 4 structural index of 0.844. In the extended structure, the cation and anion are linked by an N—H...O hydrogen bond. Along with electrostatic forces, C—H...N, C—H...S and C—H...O hydrogen bonds help to consolidate the crystal packing.

Fields of Study & Subjects

Metal complexes synthesis and properties Magnetism in coordination complexes Crystal structures of chemical compounds

Publication details

Journal / source
Acta Crystallographica Section E Crystallographic Communications
Publisher
International Union of Crystallography (IUCr)
Volume
82
Issue
2
Pages
168–172
Publication date
12 January 2026
Language
EN