Synthesis and structure of catena -poly[[[bis(pyridin-2-yl)amine]cadmium(II)]-di-μ 2 -azido]
Abstract
In the title compound, [Cd(N 3 ) 2 (C 10 H 9 N 3 )] n , the cadmium(II) ion displays a distorted CdN 6 octahedral geometry arising from one bidentate ligand and four azide ions and forms zigzag polymeric [100] chains via the bridging azide ions, both of which show μ 1,1 (end-on) coordination. Adjacent chains are linked into layers via N—H...N hydrogen bonds. Hirshfeld surface analysis was used to quantify the intermolecular interactions.
Fields of Study & Subjects
Crystal structures of chemical compounds
Crystallography and molecular interactions
Metal-Organic Frameworks: Synthesis and Applications
Publication details
- Journal / source
- Acta Crystallographica Section E Crystallographic Communications
- Volume
- 82
- Issue
- 2
- Pages
- 173–177
- Publication date
- 13 January 2026
- Language
- EN