On the Polymer Formed by Long-Term Gamma Irradiation of Benzene

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Authors: Y. M. Shulga, S. G. Vasil’ev, P. P. Kushch, G. A. Kichigina, D. P. Kiryukhin
Cited by: 2
References: 15

Abstract

Gamma irradiation of liquid benzene yielded a light yellow solid product, whose concentration increased with the radiation dose. The maximum yield (approximately 30%) was achieved at a total dose of 2.6 × 107 Gy. The product was characterized by Fourier-transform IR spectroscopy and NMR spectroscopy (1H and 13C NMR spectra). The studies revealed that the isolated product, whose composition was almost independent of radiation dose, contained both aromatic and aliphatic C–H bonds with the latter predominating. In addition to monosubstituted (terminal) benzene rings, the test polymer also contained di- and trisubstituted benzene rings. A possible structure for the polymeric product formed by gamma irradiation of liquid benzene is proposed.

Fields of Study & Subjects

Polymer Nanocomposite Synthesis and Irradiation Radiation Effects and Dosimetry Polymer composites and self-healing

Publication details

Journal / source
High Energy Chemistry
Publisher
Pleiades Publishing Ltd
Volume
60
Issue
1
Pages
96–101
Publication date
1 February 2026
Language
EN