A Series of Molybdenum Halide Cluster Complexes with Acrylate and Metacrylate Ligands

Journal of Structural Chemistry 2026

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Authors: Natalya A. Vorotnikova, Christopher Olusola Olawoyin, Alexey S. Berezin, Michael A. Shestopalov, Yuri A. Vorotnikov
DOI: 10.1134/s0022476626010208
Cited by: 0
References: 32

Abstract

Abstract We present the results of the synthesis and analysis of a series of organic-soluble cluster complexes of molybdenum: (Bu4N)2[Mo6X8L6] (X = Br, I; L = –CH2=CH–COO– (acrylate, Acr–) and –CH2=C(CH3)–COO– (metacrylate, MAcr–)). The complexes are obtained by interacting (Bu4N)2[Mo6X8X6] with silver salt of the respective acid. The mentioned compounds are characterized in detail by powder and single crystal X-ray diffraction, elemental analysis, IR and NMR spectroscopy. The luminescent properties and photophysical parameters of the solid cluster complexes are studied.

Fields of Study & Subjects

Inorganic Chemistry and Materials Polyoxometalates: Synthesis and Applications Metal-Organic Frameworks: Synthesis and Applications

Publication details

Journal / source
Journal of Structural Chemistry
Volume
67
Issue
1
Pages
201–209
Publication date
1 January 2026
Language
EN