Binuclear Cadmium(II) Complexes Based on 1,2-bis-{(2,4,6-trimethylphenyl)}Iminoacenaphthene: Synthesis, Structure, and Electrochemical Properties

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Authors: Е.В. Чехов, I.V. Bakaev, V.I. Komlyagina, A.A. Ulantikov, N. F. Romashev, A. L. Gushchin
Cited by: 1
References: 38

Abstract

Abstract Dimeric cadmium complexes based on 1,2-bis-{(2,4,6-trimethylphenyl)}iminoacenaphthene (tmp-bian) are obtained. Their compositions are [{Cd(tmp-bian)Br}2(μ-Br)2] (1) and [{Cd(tmp-bian)I}2(μ-I)2] (2). The compounds synthesized are characterized by the elemental analysis, 1H NMR and IR spectrometry. Molecular structures of 1 and 2 are determined by single crystal X-ray diffraction. The electrochemical properties of the compounds are studied by cyclic voltammetry.

Fields of Study & Subjects

Organic Light-Emitting Diodes Research Synthesis and Properties of Aromatic Compounds Metal complexes synthesis and properties

Publication details

Journal / source
Journal of Structural Chemistry
Publisher
Pleiades Publishing Ltd
Volume
67
Issue
4
Pages
787–795
Publication date
1 April 2026
Language
EN