Oxonium Derivative of Manganacarborane 1,1,1-(CO)3-6-C4H8O-isonido-1,2,4-MnC2B8H9
Abstract
The reaction of the anionic complex [1,1,1-(CO)3-isonido-1,2,4-MnC2B8H10]–X+ (X = Na, PPN+, tmndH+) with THF in the presence of initiators (BF3·Et2O, H2SO4, AlCl3) leads to the formation of the neutral complex 1,1,1-(CO)3-6-C4H8O-isonido-1,2,4-MnC2B8H9 with a THF molecule at the boron atom in the B6 position of the carborane ligand. Structure of the complex was established by multinuclear NMR, IR spectroscopy, and elemental analysis methods.
Fields of Study & Subjects
Boron Compounds in Chemistry
Boron and Carbon Nanomaterials Research
Heme Oxygenase-1 and Carbon Monoxide
Publication details
- Journal / source
- Russian Journal of General Chemistry
- Publisher
- Pleiades Publishing Ltd
- Volume
- 96
- Issue
- 4
- Publication date
- 24 February 2026
- Language
- EN