Synthesis of Acylaminoperimidines by the Reaction of 1,8-Naphthylenediamine with Nitroketones

Russian Journal of General Chemistry 2026

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Authors: Aleksandr V. Aksenov, Igor Yu. Grishin, Vladimir V. Malyuga, Дмитрий А. Аксенов, Rolena G. Dzhioeva, Nicolai A. Aksenov
DOI: 10.1134/s1070363225606957
Cited by: 0
References: 26

Abstract

Abstract The reaction of 1,8-naphthylenediamine with α-nitoketones yielded 9-acetyl- and 6(7)-acetamidoperimidines. The reaction exhibits high atom economy and is based on a tandem of benzoylation reactions of the diamine involving nitoketones, and an acylation-amination of arenes in polyphosphoric acid (PPA) medium, using the acyl forms of nitroalkanes liberated in the first stage. The dependence of the transformation’s course on the concentration of polyphosphoric acid has been investigated.

Fields of Study & Subjects

Organic and Inorganic Chemical Reactions Chemical Synthesis and Reactions Chemical Reaction Mechanisms

Publication details

Journal / source
Russian Journal of General Chemistry
Volume
96
Issue
2
Publication date
1 February 2026
Language
EN