The use of nitrocellulose production waste for energy generation

The US Army Engineer Research and Development Center investigated the use of nitrocellulose (NC) fines, an ammunition waste, for energy generation. NC is a natural high polymer obtained from treating cotton or wool with nitric and sulfuric acid. It is widely used in the industry, with military applications being the largest use currently. Since military applications range from bullet propellants to missiles for tube munitions, large quantities must be produced to meet the demand. However, large NC production batches result in large quantities of NC fines waste, generated in the form of insoluble fibers in suspension in wastewater after manufacturing. Hence, a method to reuse this generated waste and convert it into energy was tested. This study evaluated the potential of creating energy from NC waste through hydrothermal liquefaction and gasification of NC, yielding methane (CH₄) as the final product. Results demonstrated that the CH₄ concentrations increased as the temperature, reaction time, and catalyst addition were increased, yielding a maximum concentration of 2,000 ppm (6,400 peak area of the chromatograph). The homogenous catalyst performed better than the heterogenous catalyst, since it increased the CH₄ yield up to 6 times the concentration obtained with no catalyst added.