Data characterizing liquid and gas-phase products of hydrogenolysis under reactive separation at high conversion

Catalytic polymer deconstruction, as part of strategies to manage carbon resources and solid waste, is predicated on an assumption that advances and foundational insights from sealed-batch experiments will be transferable to continuous processes. This investigation quantified and characterized all hydrocarbon products from catalytic hydrogenolysis of polyolefins under a flowing reactive/carrier gas in a semi-flow reactor for kinetic and mechanistic comparisons to typical experiments in sealed batch reactors. This dataset characterizes the products from these hydrogenolysis reactions using GC-FID for headspace gases, GC-MS, GC-FID for liquids, and NMR. Files include .csv, .emf, .pdf, and .fid formats.