Spin Crossover in a Fe(II) Complex with a Radical Iminosemiquinonate Ligand

ChemRxiv 2026 Preprint Open access

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Authors: I Haseena Ismail, Jett T. Janetzki, Florian Daumann, Robert W. Gable, Jack K. Clegg, Birgit Weber, Lorenzo Sorace, Marcus J. Giansiracusa, Lars Goerigk, Colette Boskovic
DOI: 10.26434/chemrxiv.15000229/v1
Cited by: 1

Abstract

Metal complexes that exhibit spin crossover (SCO)-a reversible interconversion between lowspin (LS) and high-spin (HS) states-or valence tautomerism (VT)-an intramolecular electron transfer between a metal center and a redox-active ligand-are promising candidates for molecular materials for sensing, display, and spintronic applications. In an exploration of the

Fields of Study & Subjects

Magnetism in coordination complexes Metal-Catalyzed Oxygenation Mechanisms Organic Light-Emitting Diodes Research

Publication details

Journal / source
ChemRxiv
Publisher
American Chemical Society (ACS)
Publication date
19 February 2026
Document type
Preprint