A Stable 3D 12×12×12-Ring Zeolite Driven by 2D-to-3D Topotactic Condensation

ChemRxiv 2026 Preprint Open access

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Authors: Aimin Gong, Yuanhao Li, Yifei Yan, Ye Song, Yida Zhou, Jianguo Ding, Lisu Bai, Delun Ren, Qingfang Lin, Xiaobo Chen, Hua Deng, Shutao Xu
+4 more Wei Lin, Peng Guo, Fei‐Jian Chen, Jinghua Yu
DOI: 10.26434/chemrxiv.15001312/v1
Cited by: 1

Abstract

Stable zeolites with three-dimensional (3D) interconnected large-pore channels are crucial in industrial applications such as catalysis, adsorption, and separation.However, synthesizing these novel zeolites, especially high-silica forms, remains challenging.Here, guided by structural analysis, we designed an organic structure-directing agent (OSDA) enriched with cyclohexyl fragments to stabilize terminal bea CBUs, enabling the synthesis of a novel 2D large-

Fields of Study & Subjects

Zeolite Catalysis and Synthesis Mesoporous Materials and Catalysis Surface Chemistry and Catalysis

Publication details

Journal / source
ChemRxiv
Publisher
American Chemical Society (ACS)
Publication date
26 March 2026
Document type
Preprint