Investigating thermodynamics of liquid Li(1–X)CsX alloys

High Temperatures-High Pressures 2026 Open access

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Authors: Rajesh C. Malan, Aditya M. Vora, Priyank Kumar, S. H. Bhatt, B. K. Das
DOI: 10.32908/hthp.v54.2019
Cited by: 0

Abstract

The present article is aimed to find the various contribution towards internal energy (Eint) and Helmholtz free energy (FH) of the liquid binary alloys Li(1–X)CsX. Together with the free energy of the electron gas (Feg), Madelung contribution (Fm) average translational kinetic energy and perturbation components (F1) and (F2), the internal energy (Eint) is computed. The internal energy (Eint) and entropy (S) of the system are used in the variational method to calculate the Helmholtz free energy (FH). The pseudopotential given by Fiolhais et al is used for the present calculations. The thermodynamical quantities are presented with eight different screening and exchange and correlation functions.

Fields of Study & Subjects

Thermodynamic and Structural Properties of Metals and Alloys Metallurgical Processes and Thermodynamics Advanced Chemical Physics Studies

Publication details

Journal / source
High Temperatures-High Pressures
Volume
54
Issue
5
Pages
379–388
Publication date
1 January 2026
Language
NR