Compact Analytic Two-Gaussian Representation of Universal Short-Range Coulomb Correlations in Soft-Core Fluids

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Authors: Hiroshi Frusawa
Cited by: 1
References: 59

Abstract

Soft-core Coulomb fluids, exemplified by the two-dimensional Gaussian-charge one-component plasma, serve as fundamental benchmarks for both mathematical theory and computational modeling of coarse-grained dynamics, including stochastic density functional theory, dynamical density functional theory, and dissipative particle dynamics. In these systems, the conventional mean-field description, or the random phase approximation (RPA), is frequently employed due to its analytic simplicity; however, its validity is restricted to weak coupling regimes. Here we demonstrate that Coulomb correlations induce a structural crossover to a strongly correlated liquid where the nearest-neighbor distance saturates rather than decreasing monotonically, a behavior fundamentally incompatible with mean-field predictions. Central to our analysis is the emergence of a universal scaling law: when rescaled by the coupling constant, the short-range direct correlation function (DCF) collapses onto a single curve across the strong coupling regime. Exploiting this universality, we construct a closed-form analytic representation of the DCF using a two-Gaussian basis. This compact form accurately reproduces hypernetted-chain radial distribution functions and structure factors while ensuring exact compliance with thermodynamic sum rules. Beyond theoretical elegance, the proposed kernel offers a computationally efficient alternative to RPA-based approximations, enabling real-space dynamical methods to incorporate strong correlations without modifying long-range smoothed-charge electrostatics. Its analytic transparency bridges rigorous integral equation theory and practical dynamical kernels, additionally providing a physics-informed prior for emerging machine-learning models. Collectively, these results establish a mathematically rigorous testbed for advancing the modeling of strongly correlated soft matter systems.

Fields of Study & Subjects

Block Copolymer Self-Assembly Material Dynamics and Properties Pickering emulsions and particle stabilization

Publication details

Journal / source
Axioms
Publisher
MDPI AG
Volume
15
Issue
2
Pages
123–123
Publication date
6 February 2026
Language
EN