Polymer-Modified Fiber-Reinforced Electrically Conductive Composites with Enhanced Bond Properties

This study examines the combined effects of styrene–butadiene rubber (SBR) latex and fiber reinforcement on the mechanical and electrical properties of a high-performance fiber-reinforced composite (HPFRC). Mixtures incorporating steel fibers (SF, 0–4.5%), carbon fibers (CF, 0–1%), and hybrid SF/CF systems were evaluated, with 10–20% of the mixing water replaced by SBR. Electrical resistivity, rheological behavior, mechanical properties, and durability-related parameters were assessed and compared with plain and fiber-reinforced mixtures. Results showed that SBR significantly improved rheological behavior, flexural performance, durability, and interfacial bonding, while moderately enhancing compressive strength. The incorporation of fibers led to reduced electrical resistivity, with CF being more effective than SF, and the lowest resistivity of 4 Ω·m was achieved using a hybrid system of 0.25% CF and 1.5% SF. The addition of SF up to 1.5% increased compressive strength by up to 21%, whereas CF at 0.5% yielded the highest strength of 120 MPa. Durability indicators, including water absorption, sorptivity, and ultrasonic pulse velocity, were significantly improved at low SBR and fiber dosages. Interfacial treatment with SBR enhanced slant shear and pull-off strengths by up to 75% and 121%, respectively, confirming the effectiveness of polymer modification for multifunctional and repair-oriented HPFRC applications.