Multi-Source Integration for Assessing Air Quality Dynamics in China: The Interplay of Anthropogenic Drivers, Meteorology, and Topography

Air pollution remains a major public health and environmental challenge in China, driven by complex non-linear interactions among anthropogenic activities, meteorological conditions, and topographic features that go beyond simple linear relationships. This study presents a comprehensive spatio-temporal assessment of key air pollutants (CO, NO2, SO2, and PM2.5) and their relationships with Total Column Ozone (TCO) across China’s provinces from 2019 to 2023. Multi-source high-resolution satellite data from Sentinel-5P/TROPOMI, the China High PM2.5 dataset, MODIS, and ERA5-Land reanalysis were integrated. A tiered analytical framework was applied, combining linear Pearson correlations, non-linear Spearman rank correlations, and interpretable XGBoost machine learning with SHAP values. Results reveal a distinct seasonal “seesaw” pattern, with primary pollutants peaking during winter stagnation and TCO reaching maximum levels in late winter and spring. Non-linear analyses uncover critical threshold effects, including exponential increases in PM2.5 and SO2 when surface temperatures drop below 0 °C, very strong SO2-TCO coupling (ρ = 0.93), and significant pollutant trapping in low-elevation regions (CO-elevation ρ = −0.82). These findings support the development of precision environmental policies with dynamic, temperature-threshold-based emission controls and topography-specific strategies to effectively mitigate air pollution in China.