Deep Eutectic Solvent Based on Choline Hydroxide for Advanced Aqueous Lubrication

A novel deep eutectic solvent (DES) formulated from choline hydroxide has been investigated as an additive for advanced aqueous lubrication. Comprehensive characterization of the DES enabled the determination of its viscosity, wettability, and key spectroscopic features, providing insight into its physicochemical behavior. The tribological performance of the water-based lubricants was evaluated using a pin-on-disc configuration with a stainless steel–sapphire tribopair. The resulting friction and wear data demonstrate a significant improvement in performance, particularly for the lubricant containing 10 wt.% DES, which exhibited the most favorable reduction in wear rate, achieving an 80% decrease compared to water. Electrochemical measurements, together with surface analysis by Raman microscopy, confirmed the formation of various iron oxide phases on the wear track that influence tribological performance. These oxides contribute to the development of a protective tribolayer that enhances the overall tribological response. Complementary X-ray-based analytical techniques (EDX and XPS) further substantiated the presence, composition, and stability of this tribolayer. Therefore, the study highlights the potential of the choline hydroxide-based DES as an effective component for formulating novel water-based lubricants.